Hey pepe,
When I run: cat /dev/sndstat
My output is:
Installed devices:
pcm0: <Realtek ALC256 (Front Analog Headphones)> (play)
pcm1: <Realtek ALC256 (Rear Analog Line-out)> (play)
pcm2: <Intel Kaby Lake (HDMI/DP 8ch)> (play) default
pcm3: <BEHRINGER UMC404HD 192k> (play/rec)
Each pcm entry is a detected sound device. The one marked default is the active device.
Your output will be different but still, you have pcm0, 1, 2 and so on.
Once you know which one you want to use, edit:
sudo (editor of your choice) /etc/sysctl.conf
When the conf file opens, change this line to the number you prefer:
hw.snd.default_unit=1 (which, as you prefer, is the "second" option)
I use XFCE but this should be the same in Mate. Maybe others can confirm this or provide additional instructions.